Abstract
AbstractWe present a catalyst‐free method for indirect C−F activation of a perfluorinated side chain in C(3) position of 1H‐indoles with moderate to good yields, which allows the introduction of a nucleophile at the α‐CF2‐group of the perfluorinated chain. By adapting this approach, it is also possible to modify 3‐perfluorobutyl‐2‐phenyl‐1H‐indole to generate privileged structures for medicinal chemistry.
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