Catalyst-free growth of InAs/InxGa1−xAs coaxial nanorod heterostructures on graphene layers using molecular beam epitaxy

Abstract

We report the catalyst-free growth of InAs/InxGa1−xAs coaxial nanorod heterostructures on large-area graphene layers using molecular beam epitaxy and our investigation of the chemical composition and crystal structure of these heterostructures using electron microscopy. The graphene layers used as the substrate were prepared by chemical vapor deposition and transferred onto SiO2/Si substrates. InAs nanorods and their heterostructures were grown vertically on the graphene layers; electron microscopy images revealed uniform distributions for their diameter, length and density. Cross-sectional electron microscopy images showed that InxGa1−xAs layers, having uniform composition, coated heteroepitaxially the entire surface of the InAs nanorods, without interfacial layers or structural defects. The catalyst-free growth mechanism of InAs nanorods on graphene was investigated using in situ reflection high-energy electron diffraction. Nanorods with InAs cores and InxGa1−xAs shells have been grown catalyst-free on graphene using molecular beam epitaxy by scientists in Korea. Inorganic semiconductor nanorods on graphene layers are promising for producing electronic and optoelectronic devices that are simultaneously flexible and have long lifetimes and high efficiencies. Now, researchers at Seoul National University led by Gyu-Chul Yi have realized catalyst-free molecular beam epitaxy growth of InAs/InxGa1−xAs coaxial nanorods on graphene. This is an important step as catalyst-free molecular beam epitaxy can produce ultrapure single crystals and multilayered heterostructures with precisely-controlled thickness and chemical compositions. Analysis showed that the cores and shells were clearly defined with clean interfaces and had uniform compositions and thicknesses. This demonstration opens up the path for monolithic integration of semiconductor coaxial nanorod heterostructures on two-dimensional materials. We report the catalyst-free growth of InAs/InxGa1−xAs coaxial nanorod heterostructures on large-area graphene layers using molecular beam epitaxy and our investigation of the chemical composition and crystal structure of these heterostructures using electron microscopy. Cross-sectional electron microscopy images showed that InxGa1−xAs layers, having uniform composition, coated heteroepitaxially the entire surface of the InAs nanorods, without interfacial layers or structural defects. The catalyst-free growth mechanism of InAs nanorods on graphene was investigated using in situ reflection high-energy electron diffraction.