Abstract
An environment-friendly methodology for the synthesis of R (alkyl or aryl)-B(dan) on water is described. 1,8-diamino naphthalene(danH 2 ) was reacted with different types of organoboronic acids to furnish the products in moderate to excellent yields. A multi-gram scale reaction is also performed to ensure the scalability of the reaction. • The greenest protocol for the synthesis of Masked Haloarylboronic Acids R (Alkyl or Aryl)-B(dan). • A catalyst-free transformation under “on water” conditions. • Several examples with high-excellent yields. • Experiments to verify the theory of “on water” reaction.
Published Version
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