Year-end Sale % OFF 
Abstract
The kinetic and thermodynamic parameters of the decomposition of cumyl hydroperoxide in a chlorobenzene medium in the presence of calcium 2-ethylhexanoate and a complex of CaCl2 with crown ether were experimentally obtained. The formation of intermediate complexes in the catalyst–hydroperoxide system was kinetically established. The formation of intermediate complexes was confirmed using quantum chemical modeling, their structure was optimized, and the thermodynamic characteristics of reactions with their participation were found. A mechanism of the stepwise decomposition of the intermediate was proposed.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
