Abstract

Thermal stability, structure, and magnetic properties of bulk type Ci88.3Al2Ga1P4.35B4.35 alloy in ribbon form have been studied using differential thermal analysis, x-ray diffraction and magnetic measurements. Results reveal that crystallization peak temperature (Tx) and Curie temperature (Tc) of the as-cast alloy are respectively 513 and 370 °C. Crystallization of the specimen starts after annealing at 460 °C and α-Fe is precipitated out. Annealing at temperatures higher than 515 °C, produces apart from α-Fe, hard magnetic precipitants (Fe2B, Fe3B), which deteriorate the soft magnetic properties. Lowest coercive field – 9.8 A/m, highest saturation of induction – 1.55 Tesla and best losses – 0.42 W/kg (at 50 Hz and 0.4 kA/m) were obtained for as-cast specimen. Observed good soft magnetic properties of these low cost cast-iron based alloys suggest perspective applications of these soft magnetic alloys as an alternative to the conventional Fe-Si electrical steel and Mn-Zn ferrites.

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