Abstract

Single-layer polymer light-emitting diodes areprepared from blends of poly(N-vinylcarbozole) (PVK) doped withtris(8-hydroxy-quinoline) aluminium (Alq3) of 2 wt% (sample a)and 0.2 wt% (sample b). The onset of PVK transientelectroluminescence (EL) is delayed with respect to that of Alq3in sample a under pulsed excitation, while the EL onsets of Alq3 andPVK in sample b are simultaneous. The total carrier mobility of theAlq3-rich regions in sample a is larger than that of the PVK-richregions. However, the total carrier mobility is homogeneous in sample b.The phase image of atomic force microscopy and photoluminescencespectra of samples a and b indicate that the separated phase ofsamples a and b exists in the PVK-rich and Alq3-richregions. The variance of the doping concentration and separated phasein blends results in the different carrier transport mobility ofAlq3-rich and PVK-rich regions.

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