Abstract

AbstractA redox‐neutral, carboxylic acid promoted, [RuCl2(p‐cymene)]2 catalyzed, weakly coordinating, carbonyl assisted C−H allylation of aromatic ketones has been developed. The beneficial effect of carboxylic acid on the ruthenium catalyst towards C−H allylation of aromatic ketones has been further explored, using commercially available allyl acetate under mild reaction conditions. In addition, this method requires redox‐neutral reaction conditions, easily accessible starting materials, and shows excellent functional group compatibility.

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