Abstract
The palladium-catalyzed three-component coupling reaction of five-membered (chloromethyl)heteroarenes, allyltributylstannane, and carbon dioxide (carboxylative Stille coupling reaction) was successfully conducted to produce β,γ-unsaturated esters in satisfactory to good yields. The carboxylative Stille coupling reaction occurred smoothly under mild conditions in the presence of palladium nanoparticles through the formation of π-allylpalladium chloride intermediates.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
