Abstract

Abstract Ti3O(OiPr)6(OOC-adamantyl)4 and Ti3O2(OiPr)3(OOCCPh3)5 were obtained from the reaction of Ti(OiPr)4 with adamantylcarboxylic or triphenylacetic acid, respectively. The structures of both are based on a central Ti3O unit, which is substituted by different numbers of bridging carboxylate ligands and, in the case of the adamantyl derivative, also a chelating one.

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