Carboxyl-functionalized hybrid monolithic column prepared by “thiol-ene” click reaction for noninvasive speciation analysis of chromium with inductively coupled plasma-mass spectrometry

Abstract

A novel carboxyl-functionalized hybrid monolithic column was developed based on “thiol-ene” click reaction via “one-pot” by choosing mercaptosuccinic acid, γ-methyl methacrylate trimethoxysilane and tetramethoxysilane as reaction monomers. The design of the hybrid monolithic column was assisted by the comparison in computational simulation with existing carboxyl-functionalized materials. The characterization by scanning electron microscopy, energy dispersive X-ray spectroscopy, N2 adsorption-desorption measurement, Fourier-transform infrared spectroscopy and elemental analysis showed that the carboxyl-functionalized material has the advantages of good permeability and high mechanical strength. Then, we used the prepared carboxyl-hybrid monolith column as solid phase microextraction adsorbent for separation of trace inorganic chromium species. Under pH 4.5, the hybrid monolith column can selectively enrich Cr(III) without adsorbing Cr(VI) and afterwards, Cr(III) can be eluted by 1.0 mol L−1 HCl. The chromium speciation separation method based on carboxyl-hybrid monolith column followed by inductively coupled plasma-mass spectrometry possessed the merits of facile preparation, low cost, simple and mild extraction condition, and sensitive detection, which has been successfully applied to the separation, enrichment and detection of inorganic chromium in environmental waters.