Abstract
Reactions of the di-iron complex [Fe 2(μ-S) 2(CO) 6] 2− with carboxy-functionalized dihalide derivatives (XCH 2) 2R (X = Cl, R = NC 6H 4CH 2CO 2CH 3; X = Br, R = C 6H 3COOH, C 6H 3COON(COCH 2) 2) gave new functionalized dithiolate di-iron complexes [Fe 2(μ-SRS)(CO) 6] (R = (CH 2) 2NC 6H 4CH 2CO 2CH 3 ( 1), (CH 2) 2C 6H 3COOH ( 2), (CH 2) 2C 6H 3COON(COCH 2) 2 ( 3)) in low yields. The azadithiolate complex 1 has been characterized by a single crystal X-ray diffraction analysis and studied by electrochemical methods.
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