Abstract

Carbonylation of nickel and selectively reduced laterite ore

Highlights

  • Carbonylation of nickel obtained by reduction of nickel oxide and selectively reduced Australian laterite ore was studied at temperatures of 80-100°C and CO gauge pressures of 0–56 atm

  • The results show that the extent of nickel carbonylation increased with increasing temperature from 80 to 100°C at constant CO pressure

  • The extent of carbonylation of nickel from the selectively reduced laterite ore with particle size 53-200 μm at 100°C and CO gauge pressure 41 atm. was below 50%

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Summary

Introduction

Carbonylation of nickel obtained by reduction of nickel oxide and selectively reduced Australian laterite ore was studied at temperatures of 80-100°C and CO gauge pressures of 0–56 atm. The time for complete carbonylation of nickel was reduced from 5.5 hours in the noncatalytic reaction to 2 hours in the catalytic carbonylation at 100°C and CO gauge pressure 14 atm. The extent of carbonylation of nickel from the selectively reduced laterite ore with particle size 53-200 μm at 100°C and CO gauge pressure 41 atm.

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