Abstract
AbstractTriplet 4‐oxocyclohexadienylidenes 6, matrix‐isolated in Ar/ 2% O2 at 10 K, react with triplet O2 on annealing the matrix. Primary reaction products are quinone oxides 4, which have been characterized by IR and UV/Vis spectrometry. They are very photolabile; long‐wavelength irradiation converts them into spiro‐dioxiranes 5, which in turn yield lactones 10 upon irradiation with visible light. Experimental data have been obtained for quinone oxides 4a–g; additionally, ground‐state properties and UV/Vis absorptions of quinone oxides 4a,b and 4e–1 have been calculated by the MINDO‐3/UHF and CNDO/S methods. Since the theoretical and experimental maxima of the π → π* transitions are in good agreement, we conclude that our semiempirical calculations give an adequate picture of quinone oxides 4 which may best be described as dipolar diradicals.
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