Abstract
The title compound, [Rh(C7H3Cl2O2)(C18H15P)(CO)], is a rhodium(I) derivative of chlorinated tropolonate. It crystallizes with a nearly square-planar geometry about the rhodium(I) metal centre. The most important bond distances and angles include: Rh—O(trans P) = 2.086 (2) Å, Rh—O(trans carbonyl) = 2.056 (2) Å, Rh—P = 2.2377 (8) Å, Rh—C(carbonyl) = 1.809 (2) Å, O—Rh—O = 76.60 (6)° and O—C—C—O = −3.0 (3)°.
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