Carbonization and liquid-crystal (mesophase) development. 11. The co-carbonization of low-rank coals with modified petroleum pitches

Abstract

Coals of rank ranging from medium quality coking to non-caking, non-fusible, have been co-carbonized with Ashland petroleum pitches A170, A240 and A200 as well as pitches modified by heat-treatment with aluminium chloride using A170, and by reductive hydrogenation of the A200. The mixing ratio was 7:3, the final HTT was 873 K, heating at 10 K min −1 with a soak time of 1 h. The optical texture of the resultant cokes is assessed using polished surfaces and a polarized-light microscope using reflected light and a half-wave plate. The changes in optical texture are studied from the point of view of using coals of low rank in the making of metallurgical coke. The optical texture of resultant cokes is modified by co-carbonization and the mechanism involves a solution or solvolysis of the non-fusible coals followed by the formation of nematic liquid crystals and mesophase in the resultant plastic phase. The modified A170 pitch is more effective in modifying optical texture than the A170 because of an increase in molecular weight. The hydrogenated A200 is a very reactive additive probably because of an increased concentration of naphthenic hydrogen. The hydrogenated A200 can modify the optical texture of cokes from the organic inerts of coals and from oxidized, non-fusible coals.