Abstract

Carbon-based Quantum dots (C-QDs) are carbon-based materials that experience the quantum confinement effect, which results in superior optoelectronic properties. In recent years, C-QDs have attracted attention significantly and have shown great application potential as a high-performance supercapacitor device. C-QDs (either as a bare electrode or composite) give a new way to boost supercapacitor performances in higher specific capacitance, high energy density, and good durability. This review comprehensively summarizes the up-to-date progress in C-QD applications either in a bare condition or as a composite with other materials for supercapacitors. The current state of the three distinct C-QD families used for supercapacitors including carbon quantum dots, carbon dots, and graphene quantum dots is highlighted. Two main properties of C-QDs (structural and electrical properties) are presented and analyzed, with a focus on the contribution to supercapacitor performances. Finally, we discuss and outline the remaining major challenges and future perspectives for this growing field with the hope of stimulating further research progress.

Highlights

  • Carbon-based Quantum dots (C-QDs) are carbon-based materials that experience the quantum confinement effect, which results in superior optoelectronic properties

  • Based on the electrical charge storage mechanism, supercapacitor devices are classified into three types: electric-double-layer capacitors (EDLCs), pseudocapacitors, and hybrid supercapacitors that combines both EDLCs and pseudocapacitors

  • One of the examples is a composite of an established metal oxide or metal chalcogenide electrode materials with Carbon-based Quantum Dots (C-QDs)

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Summary

Introduction

Fossil fuel shortages and environmental concerns regarding its uses for energy generation are among the most severe challenges in achieving sustainable development. Several excellent review articles on the application of carbon-based QDs in energy conversion and storage applications, including solar cells, battery, thermoelectric devices, and supercapacitor, are reported [23,24,25]. They focus on the synthesis and the recent progress of C-QDs in applications broadly. Among the application avenues where the use of C-QDs might be distinguishable is its potential for components in electric and energy storage devices such as batteries and SCs. In this review, we provide comprehensive discussions regarding the progress and the prospect of C-QD supercapacitors.

Electric Double Layer Capacitor
Pseudocapacitor
Structural Properties
Electronic Properties
Preparation of Carbon-Based Quantum Dots
Top-Down Approach
Bottom-Up Approach
Recent Progress of Carbon-Based QD Composites
Carbon Dot Composites
O4 composites
Carbon Quantum Dot Composites
Graphene Quantum Dot Composites
Challenges and Future Perspectives
Wearable Supercapacitors
1: CuS:Ce with different
Self-Charging Supercapacitor
Findings
Conclusions
Full Text
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