Abstract
In experiments with model mixtures it is demonstrated that the de-novo-synthesis of organohalides from carbonaceous particulate matter and inorganic chloride (activated by copper ions) yields not only PCDD/PCDF but a variety of other compounds such as polychlorobenzenes (Cl 3 to Cl 6), polychloronaphthalenes and -biphenyls. In the presence of bromide also mixed chlorobromospezies are formed.
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