Abstract
The carbon-14 kinetic isotope effect for the decarbonylation of lactic acid[1-14C] in sulfuric acid has been measured in the temperature interval of 20–90°C. The experimental values of (k12C/k14C) are compared with the theoretical14C kinetic isotope effect calculated assuming that one carbon-oxygen stretching vibration is lost in the rate-determining step. The discrepancy between experimentally observed temperature dependence of the14C kinetic isotope effect and the theoretical one is explained by the possible side reactions which change the apparent degrees of decarbonylation and isotopic composition of CH3CHOHCOOH[1-14C] used in experiments aiming at the determination of carbon-14 kinetic isotope effect in the decarbonylation process itself.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Radioanalytical and Nuclear Chemistry Articles
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
