Carbon paste electrode modified by cobalt ions dispersed into poly (N-methylaniline) preparing in the presence of SDS: application in electrocatalytic oxidation of hydrogen peroxide

Abstract

Conducting and stable poly (N-methylaniline) film was prepared by using the repeated potential cycling technique in aqueous solution containing N-methylaniline, sulfuric acid, and sodium dodecyl sulfate (SDS) at the surface of carbon paste electrode (CPE). The transition metal ions of Co(ІІ) were incorporated to the polymer by immersion of the modified electrode in 0.1 M cobalt chloride solution for 10 min. The electrochemical characterization of this modified electrode exhibits stable redox behavior of Co(ІІ)→Co(ІІІ) and formation of insoluble oxide/hydroxide cobalt species on the CPE surface. The modified electrode showed well-defined and stable redox couples in alkaline aqueous solution. The modified electrode showed excellent electrocatalytic activity for oxidation of hydrogen peroxide. The response of modified electrode toward the H2O2 oxidation was examined using cyclic voltammetry, differential pulse voltammetry, square wave voltammetry, and chronoamperometry. This modified electrode has many advantages such as simple preparation procedure, good reproducibility, and high catalytic activity toward the hydrogen peroxide oxidation. Such characteristics were explored for the specific determination of hydrogen peroxide in cosmetics product sample, giving results in excellent agreement with those obtained by standard method.