Carbon nanofiber/polyethylene nanocomposite: Processing behavior, microstructure and electrical properties

Abstract

Electrically conductive polymer nanocomposite of high density polyethylene (HDPE) filled with carbon nanofibers (CNFs) were prepared by melt compounding in a batch mixer. The nanocomposite processing behavior was studied by monitoring the mixing torque vs. time as function of filler content. Scanning electron microscopy and optical microscopy were used to investigate the nanocomposite dispersion of nanofiller and the adhesion between the nanofiller and polymer matrix. The electrical and electromagnetic interference (EMI) shielding behaviors of the nanocomposite were reported as function of nanofibers concentration, and an empirical correlation related the EMI SE to the nanocomposite’s electrical resistivity was developed. Good level of CNF dispersion was evident despite the poor adhesion exhibited between the nanofibers and the HDPE matrix. At 1.5vol% CNF loading, the nanocomposite exhibited an electrical volume resistivity of 105Ω·cm. EMI shielding effectiveness was found to increase with increase in nanofiller concentration. In the 0.1–1.5GHz frequency range, 2mm thick plate made of 5vol% CNF/HDPE nanocomposite exhibits an EMI shielding effectiveness of 20dB.