Abstract
The reactions of [(η 5-C 5Me 5)(CO) 3MoCH 2Ph] and [(η 5-C 5H 4Me)(CO) 3MoCH 2-Ph] with tertiary phosphines and alkyl isocyanides in polar solvents to yield phosphine-substituted molybdenum acyl complexes have been explored and compared with the behaviour of the unsubstituted cyclopentadienyl compound. For the pentamethylcyclopentadienyl complex, reaction is restricted to tertiary phosphines with small cone angles. Unlike the cyclopentadienyl system, a mixture of cis- and trans-acyl products is formed.
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