Abstract

Carbon isotopic ratios (13C/12C) of methane, ethane and propane were analyzed for natural gases from several oil and gas fields in Niigata and Akita in Japan. A strong correlation between δ13C(C2H6) and δ13C(C3H8) was observed. This relation is well explained by a kinetic theory proposed by Chung et al. (1988). It propounds that carbon isotopic ratios of the gases are mainly decided by kinetics. on the other hand, only a weak correlation was observed between δ13C(CH4) and δ13C(C2H6). The weak correlation is inferred to be due to mixing of biogenic gas that has low δ13C(CH4). Further, δ13C of source kerogen of these gases can be calculated from δ13C(C2H6) and δ13C(C3H8). It is inferred that δ13C of source kerogen of the gases in Akita and Niigata are close to each other.

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