Carbon dots prepared by different bottom-up methods: a study on optical properties and the application as nanoprobes for metal ions detection

Abstract

Carbon dots (CDs) have emerged in the last few years as new carbon nanostructures due to their excellent optical and physicochemical properties and thus promising applications in different areas. In this work, we describe the preparation of different CDs obtained from distinct bottom-up methods and also using different low molar mass precursors in order to study advantages and disadvantages of each experimental method used. Different techniques were performed to characterize the nanoparticles, such as Transmission electron microscopy, Potentiometric titration, Fourier transform infrared, Fluorescence and Ultraviolet-visible spectroscopy. The CDs obtained using conventional hydrothermal carbonization showed the highest values of quantum yield (QY), whereas the nanoparticles obtained by the heating reflux reaction method exhibited the lowest QY values mainly due to incomplete polymerization and/or carbonization reactions of the material. In addition, a study to evaluate the use of the CDs as nanoprobes for metallic ions showed that one of the samples exhibited high selective and sensitive response toward Fe3+, with a detection limit of 0.89 µM. Furthermore, the nanoparticles used as sensors were obtained with an environmentally friendly strategy, and the CD-based photoluminescence method is simple, has a short response time and present low-cost.