Carbon Dot as Visible-Light Photoredox Catalysts for a Myriad of Organic Transformations.

Abstract

Metal-free catalysts for various organic transformations are of high demand now. In this study, we present a new carbon dot as an efficient metal-free nanophotocatalyst for carrying out a series of organic bond formation reactions. Using a single photocatalyst carbon dot, Csp2-Csp2, Csp2-B, Csp2-S, Csp2-Se, and C-P bond formation reactions were performed with a high yield of the corresponding products. Moreover, Csp2-H activation of the aromatic ring was achieved by merging the carbon dot photocatalyst with a transition metal. Interestingly, these carbon nanodot-based catalysts show good recyclability a few times without any significant loss of catalytic activity. The development of catalytic systems based on carbon dots has its merits vested in the advantageous properties of this nanomaterial, such as a robust chemical nature and cheap cost of preparation. This report demonstrates that a carbon dot indeed holds the potential to replace expensive metal-based catalysts as well as organic dyes in five different photoredox reactions.