Abstract

A new high pressure cell was developed to measure the high pressure phase behavior of gas+aqueous salt solutions and validated through the measurement, and comparison against literature data, of two systems, the H2O+CO2 and H2O+CO2+NaCl, at temperatures up to 363K and pressures up to 13MPa. As previously reported by others, a salting out effect on the carbon dioxide solubility in water by NaCl is observed, decreasing its solubility as the salt concentration increases. Electrolyte versions of the cubic-plus-association and the RKSA-Infochem equations of state were used to estimate the H2O+CO2 and H2O+CO2+NaCl phase behavior, with both EoS providing a good representation of the experimental data.

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