Carbon Dioxide Sequestration via Steelmaking Slag Carbonation in Alkali Solutions: Experimental Investigation and Process Evaluation

Abstract

Carbon dioxide mineral sequestration with steelmaking slag is a promising method for reducing carbon dioxide in a large-scale setting. Existing calcium oxide or calcium hydroxide in steelmaking slag can be easily leached by water, and the formed calcium carbonate can be easily wrapped on the surface of unreacted steelmaking slag particles. Thus, further increase in the carbonation reaction rate can be prevented. Enhanced carbon dioxide mineral sequestration with steelmaking slag in dilute alkali solution was analysed in this study through experiments and process evaluation. Operating conditions, namely alkali concentration, reaction temperature and time, and liquid-to-solid ratio, were initially investigated. Then, the material and energy balance of the entire process was calculated, and the net carbon dioxide sequestration efficiency at different reaction times was evaluated. Results showed that dilute alkali solution participated in slowing down the leaching of active calcium in the steelmaking slag and in significantly improving carbonation conversion rate. The highest carbonation conversion rate of approximately 50% can be obtained at the optimal conditions of 20 g/L alkali concentration, 2 mL/L liquid-to-solid ratio, and 70 °C reaction temperature. Carbonation reaction time significantly influences the net carbon dioxide sequestration efficiency. According to calculation, carbon dioxide emission of 52.6 kg/t-slag was avoided at a relatively long time of 120 min.