Carbon Dioxide Anion Radicals Assisted Highly Efficient Photocatalytic H2O2 Production over Bi(C2O4)OH.

Abstract

Carbon dioxide anion radical (CO2•-) can act as a versatile single electron reductant, but its generation pathways are quite limited. Herein, we demonstrate that oxalic acid (OA) could be effectively and continuously utilized to produce CO2•- over Bi(C2O4)OH, a novel photocatalyst, under light irradiation. Bi(C2O4)OH would proceed with self-redox reactions under the light irradiation producing CO2•-, through the oxidation of C2O42-. OA in the solution could recoordinate with Bi3+, thus maintaining the structure of the photocatalysts and the stability of the reactions. Benefiting from the fast reaction between CO2•- and O2 in forming •O2-, hydrogen peroxide (H2O2) would be efficiently produced (219.0 μmol/h). This study proposes a novel approach for harnessing OA containing wastewater and explores its potential application in the efficient production of H2O2.