Abstract
This review describes polymer synthesis utilizing carbon dioxide and carbon disulfide as useful C1 resources. Chain and step copolymerizations are recounted with polymerizations of cyclic carbonates, especially five-membered ones, as monomers derived or potentially obtainable from carbon dioxide. Homopolymerization, copolymerizations, and application as a precursor for reversible chain transfer agents for RAFT polymerization are described for carbon disulfide based polymer synthesis. As polymerizations of monomers from carbon disulfide, ring-opening polymerizations of dithiocarbonates and thiourethanes are described.
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