Carbon and water footprint of battery-grade lithium from brine and spodumene: A simulation-based LCA

Abstract

Increasing demand for lithium driven by e-mobility spurs the expansion of lithium projects and exploration of lower-grade resources. This article combines process simulation (HSC Chemistry) and life cycle assessment tools to develop life cycle inventories considering declining ore grades scenarios for battery-grade Li2CO3 production from pivotal sources and regions (Salar de Atacama - brine and Greenbushes - spodumene). Depending on the ore grades, climate change results range from 5,0 to 25,0 kgCO2eq/kg Li2CO3 for brine and from 17,1 to 22,3 kgCO2eq/kg Li2CO3 for spodumene. Water consumption for brine varies from 0,2 to 7,7 m3/kg Li2CO3, depending on flow accounting, while for spodumene, it ranges from 0,2 to 0,5 m3/kg Li2CO3. The research shows that decreasing ore grade can lead to a fivefold increase in the carbon footprint for brine-based production and a 1.3-fold increase for spodumene. This underscores the importance of decarbonizing energy provision for lithium production to guarantee a sustainable battery supply chain. This research offers insights into using process simulation to enhance existing LCA studies in the raw materials industry and further develop inventory datasets, considering variations such as deposit ore grades.