Abstract

THE value of carbon and oxygen isotope ratios in determining the nature of the depositional environment for various types of carbonate rocks has been pointed out by a number of workers1–3, who showed that freshwater limestones are enriched in carbon-12 and oxygen-16 relative to the marine varieties. Moreover, detailed variations in 12C/13C ratios were found to be preserved in the Vanport limestone of Pennsylvanian age4; the ratios increase regularly toward the shoreline of the estuarine–deltaic basin complex and presumably indirectly reflect variations in salinity concurrent with the mixing of carbon-12 enriched continental bicarbonate of the distributary with carbon-13 enriched bicarbonate of the ocean.

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