Abstract

The phenomenon of 13C spin diffusion offers a means by which the relative orientations of neighboring molecules may be determined. Possible applications include the determination of the binding mechanism of enzymes, the structure of amorphous polymers, and the structure of noncrystalline molecular complexes. To develop the technique, initial experiments were made on 13C-labeled zinc acetate dihydrate, for which an X-ray structure is available. The NMR results are compatible with the known orientation of the two molecules in the unit cell of this material.

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