Abstract
The hyperfine interaction with13C in nonenriched [Rh(CN)6]4−, in a KCl host lattice at 7 K, is measured by continuous-wave X- and Q-band electron paramagnetic resonance, allowing, for the first time, a comparative study of spin densities on the carbon of the axial cyanide in this complex and in the similar [Co(CN)6]4−complex. From the experimental data corrected for dipolar interactions,Aiso= 79.80 × 10−4cm−1andAanis= 0.76 × 10−4cm−1.
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