Abstract
Cadmium carbenoid was prepared from diethylcadmium and gem-diiodoalkane and its reactions were investigated. Reaction of olefins with diethylcadmium and methylene iodide gave cyclopropanes in good yield by a stereospecific cis addition. Olefin, diethylcadmium and ethylidene iodide afforded Me substituted cyclopropane, in which the anti isomer was predominant contrary to the case of the corresponding reaction with diethylzinc. Phenylsubstituted cyclopropane was obtained from the reaction of olefin with diethylcadmium and benzal iodide. The reaction was found to favour the syn isomer but less than the corresponding reaction with diethylzinc. Phenylpropadienes were obtained from phenylacetylenes, diethylcadmium and gem-diiodoalkane. On the other hand, in the corresponding reaction with diethylzinc, metallation of acetylenic compound predominated over the formation of allene.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
