Carbendazim imprinted electrochemical sensor based on CdMoO4/g-C3N4 nanocomposite: Application to fruit juice samples.

Abstract

Carbendazim (CAR) as a fungicide is utilized for fruits and vegetables to provide diseases' control and the degradation of carbendazim having benzimidazole ring is slow. Herein, a molecularly imprinted electrochemical sensor based on CdMoO4/g-C3N4 nanocomposite was prepared for CAR determination in fruit juice samples. Firstly, CdMoO4/g-C3N4 nanocomposite with high yield was fabricated via one-pot in-situ hydrothermal approach including environmentally friendly method. Formation of CAR imprinted polymers was performed on CdMoO4/g-C3N4 nanocomposite modified glassy carbon electrode (GCE) in presence of CAR as template and pyrrole (Py) as a monomer by cyclic voltammetry (CV) technique. Following the morphological, structural, and optical characterization of as-synthesized nanocomposite, the electrochemical techniques were also implemented to evaluate the electrochemical features of fabricated electrodes. The limit of quantification (LOQ) and limit of detection (LOD) values were calculated as 0.1×10-10M, and 2.5×10-12M, respectively in addition to satisfactory selectivity, stability, reproducibility and reusability. The findings revealed that the proposed CAR imprinted electrochemical sensor can be successfully employed in food safety.