Abstract
AbstractWhen a thin polymer film is spin‐coated on a solid substrate and heated above its glass transition temperature (Tg) while in conformal contact with a patterned polydimethylsiloxane (PDMS) mold, capillarity forces the polymer melt to fill up the void space of the mold, thereby forming a negative replica of the polymer after mold removal. In this study, particular emphasis is given to the nodal dewetting phenomenon in a thin, laterally confined polymer film that sticks to a substrate. When heated above the glass transition temperature, the film dewets from the substrate through the generation of nodal waves, with the PDMS wall acting as a node. Various superposed waves were observed depending on the intrinsic period of dewetting and the confining width of the cavity.
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