Capacitive deionization electrode fabrication using activated carbon derived from agriculture by-products toward industry application: A review

Abstract

Capacitive deionization (CDI), membrane capacitive deionization (MCDI), and flow capacitive deionization (FCDI) are emerging technologies applied to remove ions from brackish water or saline wastewater based on electrode double layer (EDL) mechanisms. The electrode itself can be seen as the most important factor that determines the deionization efficiency of the CDI system. Electrode fabrication using activated carbon derived from agriculture byproducts is a useful solution to decrease cost, restrict environmental pollution, and enable agriculture waste recovery. In this review, the primary parameter's impact on activated carbon (AC) and the electrode fabrication process from the agriculture byproducts is detailed in a discussion to find the most optimal conditions. With excellent characteristics for the activated carbon such as a surface area of up to 2500 m2/g, it can be used to fabricate electrodes that have a high adsorption capacity of approximately 25 mg/g, able to be advanced to 40 mg/g with a modified AC. It can achieve a cycle performance of 95-97%. The deionization efficiency of the CDI, MCDI, and FCDI systems can be up to 90% with an input salt concentration from 2000 to 3000 mg/L where the water recovery ratio achieved is 50-90%, alongside a salt rejection rate of about 7-75%. AC can be modified to increase its special properties such as surface area, conductivity, and ion selectivity using different methods. The drawbacks and challenges of the CDI technology are also mentioned along with useful solutions such as electrode coating techniques using an anilox roller and a spray, for use in industry applications.