Abstract

Differential capacitance curves on an Hg–Ga electrode are obtained in aqueous solutions of various composition. An Hg–Ga electrode containing 2.1 at. % Hg to a high accuracy models electrochemical properties of a liquid Hg electrode at negative charges. This result can justify the approach according to which studying liquid In–Ga, Tl–Ga, Cd–Ga, and Pb–Ga alloys permit qualitative characterization of lyophilic properties of corresponding solid alloys.

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