Cansolv CO2 capture: The value of integration

Abstract

Abstract If CO2 emissions are to be reduced to control global warming, many large scale projects will need to be executed on a short term that capture and sequester the CO2. Most studies to date have focused on CO2 capture from power plant flue gas and concluded that the cost of CO2 scrubbing is in itself expensive and that more mature and efficient technologies are needed. CO2 emission control is also complicated by the need to provide SO2 and NOx emission control as well. Burner modifications can be used to control NOx, but other scrubbing technologies are needed to control SO2 emissions. For high sulfur coals, limestone scrubbing is generally applied, adding to the cost of power through purchases of limestone reagent and disposal of by-product gypsum. Cansolv has evolved amine based regenerable technologies that capture SO2 and CO2 and that release them in a water wet, nearly pure condition. SO2 can be converted to sulfuric acid and CO2 can be dried, compressed and sequestered without further treatment. Most importantly, energy used to capture SO2 can be recycled to help capture CO2, reducing the net energy demand of the CO2 process. The use of these two technologies together allows power companies to use higher sulfur, lower cost fuels and reduce energy consumption rates for CO2 capture. By-product sulfuric acid from the SO2 scrubbing system also provides a ready source of revenue to offset scrubbing costs. Cansolv has proven its SO2 scrubbing technologies in commercial applications since 2002. It has operated CO2 pilot plants at several different locations, logging over 6,000 hours of operation. The two technologies will come together in an integrated system, in a plant designed to generate 50 tons per day of CO2, which will start up in 2009. This paper presents important design and performance advantages of these systems.