Abstract

A new approach to unravel the site symmetry of lanthanides in solutions is presented. The magnetic circular dichroism spectra of Eu 3+ in the symmetries D 3 h , C 4 v and D 2 d are simulated. In these simulations, the main idea is to introduce the magnetic field along a 3-fold axis, being the resultant of the three equivalent X-, Y- and Z-direction of a cube. This implies that the parallel and perpendicular Zeeman effects are taken into account simultaneously.

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