Abstract

With limited resources as a driver, the search for novel materials for improved desalination processes has been a major component of water research in recent years. Graphene and its derivatives are one such promising material. Graphene is a 2D material, which exhibits remarkable strength and durability, has a very high specific surface area, is easily modified and has high thermal and electrical conductivity. As a result, it is a candidate material for a remarkable range of desalination applications, including in membranes for separation processes, direct solar thermal desalination and electrolytic desalination processes. This review paper describes the background and properties of interest for desalination processes and reviews the recent literature for graphene compounds used in membrane processes (including reverse osmosis, nanofiltration, forward osmosis, membrane distillation, pervapouration, electrodialysis), capacitive deionisation and solar desalination. Overall, high permeability combined with high salt rejection compared with conventional materials for these applications, suggest that these materials could potentially revolutionise desalination if they can be produced at commercial scales at competitive costs.

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