Abstract
The paper presents the first worldwide, original, thermodynamic measurements for LiPt system. The partial and integral molar enthalpy of mixing of liquid LiPt alloys was determined with the use of MHTC 96 drop calorimeter. The measurements for this binary system were carried out at four different temperatures (622 K, 722 K, 824 K, 926 K), up to a maximum platinum content equalled xPt = 0.34. The values of the integral molar enthalpies of mixing were negative in the entire studied concentration range. The experimental data of liquid LiPt solutions were elaborated by the Redlich-Kister equation. This study has begun the experimental measurements of the LiPt system.
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