Calibration model with skew scale mixtures of normal distributions

Abstract

ABSTRACTThis work presents a new linear calibration model with replication by assuming that the error of the model follows a skew scale mixture of the normal distributions family, which is a class of asymmetric thick-tailed distributions that includes the skew normal distribution and symmetric distributions. In the literature, most calibration models assume that the errors are normally distributed. However, the normal distribution is not suitable when there are atypical observations and asymmetry. The estimation of the calibration model parameters are done numerically by the EM algorithm. A simulation study is carried out to verify the properties of the maximum likelihood estimators. This new approach is applied to a real dataset from a chemical analysis.