Calculations of the Binding-Energy Differences for Highly-Charged Ho and Dy Ions

Abstract

The binding-energy differences for ^{{163}}{text{H}}{{{text{o}}}^{{q + }}} and ^{{163}}{text{D}}{{{text{y}}}^{{q + }}} ions with ionization degrees q = 38, 39, and 40 are calculated. The calculations are performed using the large-scale relativistic configuration-interaction and relativistic coupled-clusters methods. The contributions from quantum-electrodynamics, nuclear-recoil, and frequency-dependent Breit-interaction effects are taken into account. The final uncertainty does not exceed 1 eV. Combining the obtained results with the binding-energy difference for neutral atoms calculated in [I.M. Savelyev, M.Y. Kaygorodov, Y.S. Kozhedub, I.I. Tupitsyn, and V.M. Shabaev, Phys. Rev. A 105, 012806 (2022)], we get the secondary differences of the ion–atom binding energies. These values can be used to evaluate the amount of energy released in the electron capture process in ^{{163}}{text{Ho}} atom (the Q value), provided mass differences of highly charged ions ^{{163}}{text{H}}{{{text{o}}}^{{q + }}} and ^{{163}}{text{D}}{{{text{y}}}^{{q + }}} is known from experiment. The Q value is required by experiments on the determination of the absolute scale of the electron neutrino mass by studying the beta-decay process.