Abstract

The binding-energy differences for163Hoq+and163Dyq+ions with ionization degreesq=38, 39, and 40 are calculated. The calculations are performed using the large-scale relativistic configuration-interaction and relativistic coupled-clusters methods. The contributions from quantum-electrodynamics, nuclear-recoil, and frequency-dependent Breit-interaction effects are taken into account. The final uncertainty does not exceed 1 eV. Combining the obtained results with the binding-energy difference for neutral atoms calculated in [I.M.Savelyev, M.Y. Kaygorodov, Y.S. Kozhedub, I.I. Tupitsyn, and V.M. Shabaev, Phys. Rev. A105, 012806 (2022)], we get the secondary differences of the ion–atom binding energies. These values can be used to evaluate the amount of energy released in the electron capture process in163Hoatom (theQvalue), provided mass differences of highly charged ions163Hoq+and163Dyq+is known from experiment. TheQvalue is required by experiments on the determination of the absolute scale of the electron neutrino mass by studying the beta-decay process.

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