Calculations of stretching vibrational overtones and combinations of arsine by nonlinear model

Abstract

A three-parameter nonlinear model in nonlinear quantum theory, i. e., the quantized discrete self-trapping equation, has been used to calculate the vibrational energy spectrum, including the overtones and combinations with many excited quanta, of AsH stretches of arsine, AsH3. The model calculations agree well with experiment and other calculations. It is shown that the dominant feature of the energy spectrum of AsH3 molecule is a pattern of local mode pairs, and that when n ≥ 4, all the vibrational energies are almost localized on a single AsH bond.