Abstract
Gibbs energies have been modeled for the binary alloy systems Ag-Cu and Cd-Zn, simple eutectic systems of interest in the area of rapid solidification. Parameters of the thermodynamic functions are derived from phase diagram and thermochemical data. Metastable phase equilibria have then been calculated, as well as the chemical spinodals and the locus of compositions and temperatures where liquid and solid have equal Gibbs energies (T 0).
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