Abstract
The effective spin-Hamiltonian (SH) parameters (zero-field splitting D and g factors g ∥ and g ⊥) for Cr 3+ ions in LiSr(Al,Ga)F 6 crystals are calculated from the complete high-order perturbation formulae for a d 3 ion. Parameters of trigonal crystal field acting on the Cr 3+ ion are calculated. The magnitude of trigonal distortion of the [CrF 6] 3− clusters is related to the experimental measurements of the spin-Hamiltonian parameters in the considered systems. Since in both crystals g ∥< g ⊥, [CrF 6] 3− clusters undergo an axial compression along the C 3 axis. Experimental values of the hyperfine structure constants A ∥ and A ⊥ are used to evaluate the core polarization constant κ for Cr 3+ ion in both crystals.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
