Abstract
Recently, neutron diffraction data obtained with a fully deuterated sample of the nematic liquid crystal para-azoxyanisole (PAA) were reported. In the present paper a number of simple ideas which contribute to an understanding of these data are presented. It is shown that part of the structure of the observed diffraction patterns can be attributed to the wavelength dependence of a molecular form-factor. Further, it is found that diffuse scattering observed in PAA just below its melting point may be explained in terms of oscillations of molecules about their long axes. The temperature dependence of this diffuse scattering suggests that the melting of PAA may be driven by a soft torsional mode or modes. The explanation of the diffuse scattering from the solid and the similarities between the diffraction patterns of solid and nematic phases suggest that scattering from the nematic phase might be explicable in terms of hindered rotations of molecules about their long axes. A simple model based on this hypothesis and on the neglect of short-range orientational correlations of the molecular long axes is proposed. A comparison of results obtained from this model with the experimental data demonstrates that there is considerable short-range ordering of the long molecular axes in both the nematic and isotropic-liquid phases of PAA.
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