Abstract
A thermodynamic evaluation of the ZrO[ 2-MgO system has been conducted and combined with the previous descriptions of the ZrO 2-CaO and MgO-CaO systems to calculate the ZrO 2-CaO-MgO phase diagram by means of Bonnierś equation. The calculated results are shown by isothermal sections, a projection of the Liquidus surfaces, and a reaction scheme. Comparisons between the computed and experimental diagrams demonstrate that the calculations reasonably account for the experimental data and no ternary parameter is necessary for the description of the ZrO 2-CaO-MgO system.
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