Abstract

Abstract We solve the Schrodinger equation with the improved expression of the Manning–Rosen empirical potential energy model. The rotation-vibrational energy spectra and the unnormalized radial wave functions have been obtained. The interaction potential energy curve for the a 3 Σ u + state of Li 2 7 molecule is modeled by employing Manning–Rosen potential model. Favorable agreement for the Manning–Rosen potential is found in comparing with ab initio data. The vibrational energy levels predicted by using the Manning–Rosen potential for the a 3 Σ u + state of Li 2 7 are in good agreement with the RKR data and ab initio determinations.

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